Non-equilibrium crystallization pathways of manganese oxides in aqueous solution
Multistage crystallization of transition metal oxides often proceeds through a number of metastable intermediates. Here, the authors shed light on this phenomenon by extending Pourbaix diagrams to capture the metastable and nanoscale thermodynamics of manganese oxide nucleation.
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Format: | Article |
Language: | English |
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Nature Portfolio
2019-02-01
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Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/s41467-019-08494-6 |
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author | Wenhao Sun Daniil A. Kitchaev Denis Kramer Gerbrand Ceder |
author_facet | Wenhao Sun Daniil A. Kitchaev Denis Kramer Gerbrand Ceder |
author_sort | Wenhao Sun |
collection | DOAJ |
description | Multistage crystallization of transition metal oxides often proceeds through a number of metastable intermediates. Here, the authors shed light on this phenomenon by extending Pourbaix diagrams to capture the metastable and nanoscale thermodynamics of manganese oxide nucleation. |
first_indexed | 2024-12-14T14:40:29Z |
format | Article |
id | doaj.art-5f44a48242594b3690b486f98ef488ed |
institution | Directory Open Access Journal |
issn | 2041-1723 |
language | English |
last_indexed | 2024-12-14T14:40:29Z |
publishDate | 2019-02-01 |
publisher | Nature Portfolio |
record_format | Article |
series | Nature Communications |
spelling | doaj.art-5f44a48242594b3690b486f98ef488ed2022-12-21T22:57:26ZengNature PortfolioNature Communications2041-17232019-02-011011910.1038/s41467-019-08494-6Non-equilibrium crystallization pathways of manganese oxides in aqueous solutionWenhao Sun0Daniil A. Kitchaev1Denis Kramer2Gerbrand Ceder3Materials Sciences Division, Lawrence Berkeley National LaboratoryDepartment of Materials Science and Engineering, Massachusetts Institute of TechnologyEngineering Sciences, University of SouthamptonMaterials Sciences Division, Lawrence Berkeley National LaboratoryMultistage crystallization of transition metal oxides often proceeds through a number of metastable intermediates. Here, the authors shed light on this phenomenon by extending Pourbaix diagrams to capture the metastable and nanoscale thermodynamics of manganese oxide nucleation.https://doi.org/10.1038/s41467-019-08494-6 |
spellingShingle | Wenhao Sun Daniil A. Kitchaev Denis Kramer Gerbrand Ceder Non-equilibrium crystallization pathways of manganese oxides in aqueous solution Nature Communications |
title | Non-equilibrium crystallization pathways of manganese oxides in aqueous solution |
title_full | Non-equilibrium crystallization pathways of manganese oxides in aqueous solution |
title_fullStr | Non-equilibrium crystallization pathways of manganese oxides in aqueous solution |
title_full_unstemmed | Non-equilibrium crystallization pathways of manganese oxides in aqueous solution |
title_short | Non-equilibrium crystallization pathways of manganese oxides in aqueous solution |
title_sort | non equilibrium crystallization pathways of manganese oxides in aqueous solution |
url | https://doi.org/10.1038/s41467-019-08494-6 |
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