Chemical composition and distribution of the headspace volatiles in commercial culinary herbs and spices: Chemometric approach

Fast determination of the volatile components of widely used culinary herbs and spices, without prior preparation of the sample, using headspace sampling (HS) and GC–MS/FID analysis, is presented. Generally, monoterpenes were the dominant class in HS volatiles (HSV): monoterpene hydrocarbons in dill...

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Main Authors: Jovanović Snežana Č., Jovanović Olga P., Mitić Zorica S., Petrović Goran M., Stojanović Gordana S.
Format: Article
Language:English
Published: Serbian Chemical Society 2020-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2020/0352-51392000007J.pdf
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author Jovanović Snežana Č.
Jovanović Olga P.
Mitić Zorica S.
Petrović Goran M.
Stojanović Gordana S.
author_facet Jovanović Snežana Č.
Jovanović Olga P.
Mitić Zorica S.
Petrović Goran M.
Stojanović Gordana S.
author_sort Jovanović Snežana Č.
collection DOAJ
description Fast determination of the volatile components of widely used culinary herbs and spices, without prior preparation of the sample, using headspace sampling (HS) and GC–MS/FID analysis, is presented. Generally, monoterpenes were the dominant class in HS volatiles (HSV): monoterpene hydrocarbons in dill, celery, parsnip and parsley, and oxygenated monoterpenes in coriander, bay laurel and rosemary. The HSV of ginger and clove samples differed from the others due to their high content of sesquiterpene hydrocarbons and phenylpropanoids, respectively. The most extreme case of limited distribution was related to the samples of garlic-HSV comprised organosulfur compounds and none of the above mentioned classes. Furthermore, the HSV data were processed via principal component analysis, making visible the variability and tendency between the investigated samples. Lastly, the research provides insights in many HS profiles of culinary herbs and spices, giving relative representation of volatiles as well as differences and deviation in terms of HSV content. [Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. 172047]
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spelling doaj.art-5fe50fbba27143b083b00305e2ef69e02022-12-21T21:17:51ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212020-01-018581001101010.2298/JSC191121007J0352-51392000007JChemical composition and distribution of the headspace volatiles in commercial culinary herbs and spices: Chemometric approachJovanović Snežana Č.0Jovanović Olga P.1Mitić Zorica S.2Petrović Goran M.3Stojanović Gordana S.4Department of Chemistry, Faculty of Sciences and Mathematics, University of Niš, Niš, SerbiaDepartment of Chemistry, Faculty of Sciences and Mathematics, University of Niš, Niš, SerbiaDepartment of Biology and Ecology, Faculty of Sciences and Mathematics, University of Niš, Niš, SerbiaDepartment of Chemistry, Faculty of Sciences and Mathematics, University of Niš, Niš, SerbiaDepartment of Chemistry, Faculty of Sciences and Mathematics, University of Niš, Niš, SerbiaFast determination of the volatile components of widely used culinary herbs and spices, without prior preparation of the sample, using headspace sampling (HS) and GC–MS/FID analysis, is presented. Generally, monoterpenes were the dominant class in HS volatiles (HSV): monoterpene hydrocarbons in dill, celery, parsnip and parsley, and oxygenated monoterpenes in coriander, bay laurel and rosemary. The HSV of ginger and clove samples differed from the others due to their high content of sesquiterpene hydrocarbons and phenylpropanoids, respectively. The most extreme case of limited distribution was related to the samples of garlic-HSV comprised organosulfur compounds and none of the above mentioned classes. Furthermore, the HSV data were processed via principal component analysis, making visible the variability and tendency between the investigated samples. Lastly, the research provides insights in many HS profiles of culinary herbs and spices, giving relative representation of volatiles as well as differences and deviation in terms of HSV content. [Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. 172047]http://www.doiserbia.nb.rs/img/doi/0352-5139/2020/0352-51392000007J.pdfchemical compositionspiceherbshs-gc-ms/fidprincipal component analysis
spellingShingle Jovanović Snežana Č.
Jovanović Olga P.
Mitić Zorica S.
Petrović Goran M.
Stojanović Gordana S.
Chemical composition and distribution of the headspace volatiles in commercial culinary herbs and spices: Chemometric approach
Journal of the Serbian Chemical Society
chemical composition
spice
herbs
hs-gc-ms/fid
principal component analysis
title Chemical composition and distribution of the headspace volatiles in commercial culinary herbs and spices: Chemometric approach
title_full Chemical composition and distribution of the headspace volatiles in commercial culinary herbs and spices: Chemometric approach
title_fullStr Chemical composition and distribution of the headspace volatiles in commercial culinary herbs and spices: Chemometric approach
title_full_unstemmed Chemical composition and distribution of the headspace volatiles in commercial culinary herbs and spices: Chemometric approach
title_short Chemical composition and distribution of the headspace volatiles in commercial culinary herbs and spices: Chemometric approach
title_sort chemical composition and distribution of the headspace volatiles in commercial culinary herbs and spices chemometric approach
topic chemical composition
spice
herbs
hs-gc-ms/fid
principal component analysis
url http://www.doiserbia.nb.rs/img/doi/0352-5139/2020/0352-51392000007J.pdf
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