Pyrene-Based Diarynes as Precursors for Twisted Fused Polycyclic Aromatic Hydrocarbons: A Comparison of Two Routes

Abstract Two bench-stable and readily accessible pyrene-based diaryne precursors based on triflate as well as TMS triflate motifs are introduced and compared in their [4+2]-Diels–Alder reactions with tetracyclone to give an oligophenyl-substituted dibenzo[e,l]pyrene in both cases. By single-crystal...

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Bibliographic Details
Main Authors: Sven M. Elbert, Kevin Baumgärtner, Joshua A. Esteves, Laura Weber, Frank Rominger, Michael Mastalerz
Format: Article
Language:English
Published: Georg Thieme Verlag 2020-10-01
Series:Organic Materials
Subjects:
Online Access:http://www.thieme-connect.de/DOI/DOI?10.1055/s-0040-1721851