Asymmetric Synthesis of Spirooxindoles via Nucleophilic Epoxidation Promoted by Bifunctional Organocatalysts

Asymmetric Synthesis of Spirooxindoles via Nucleophilic Epoxidation Promoted by Bifunctional Organocatalysts

Taking into account the postulated reaction mechanism for the organocatalytic epoxidation of electron-poor olefins developed by our laboratory, we have investigated the key factors able to positively influence the H-bond network installed inside the substrate/catalyst/oxidizing agent. With this aim,...

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Bibliographic Details
Main Authors: Martina Miceli, Andrea Mazziotta, Chiara Palumbo, Elia Roma, Eleonora Tosi, Giovanna Longhi, Sergio Abbate, Paolo Lupattelli, Giuseppe Mazzeo, Tecla Gasperi
Format: Article
Language:English
Published: MDPI AG 2018-02-01
Series:Molecules
Subjects:
epoxidation
organocatalysis
epoxyoxindole
alkylidenoxindoles
H-bond network
non-covalent catalysis
chiroptical properties
Online Access:http://www.mdpi.com/1420-3049/23/2/438

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http://www.mdpi.com/1420-3049/23/2/438

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