Pd/Cu-Catalyzed Cross-Coupling of Bis(2-bromovinyl) Selenides with Terminal Acetylenes: Unusual Involvement of Selanyl Function in the Sonogashira Reaction

Pd/Cu-Catalyzed Cross-Coupling of Bis(2-bromovinyl) Selenides with Terminal Acetylenes: Unusual Involvement of Selanyl Function in the Sonogashira Reaction

The Pd/Cu-catalyzed Sonogashira reaction of (<i>E,E</i>)-bis(2-bromovinyl) selenide and (<i>E,E</i>)-bis(1-bromo-1-hexen-2-yl) selenide with terminal alkynes was found to proceed at room temperature involving both bromine atoms and the selanyl function. As a result, new bis-(...

Full description

Bibliographic Details
Main Authors: Alexander V. Martynov, Nataliya A. Makhaeva, Maxim V. Musalov, Alexander I. Albanov, Svetlana V. Amosova
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Catalysts
Subjects:
2-bromovinyl selenides
cross-coupling
palladium catalyst
terminal acetylenes
endiynes
bis-(enynyl) selenides
Online Access:https://www.mdpi.com/2073-4344/12/12/1589

Internet

https://www.mdpi.com/2073-4344/12/12/1589

Similar Items