Tributyl[2-(trimethylsilyl)-prop-2-enyl]stannane: A Highly Efficient Reagent for the Allylation of Radicals
Allylation rates of radicals with tributyl[2-(trimethylsilyl)prop-2-enyl]stannane (2) have been compared with the ones of the (prop-2-enyl)stannane (3) and [2-(methyl)-prop-2-enyl]stannane (4). The Me3Si substituent showed a rate-accelerating effect (4.2:1 to 6.5:1) relati ve to the H-atom...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | deu |
Published: |
Swiss Chemical Society
1994-09-01
|
Series: | CHIMIA |
Online Access: | https://www.chimia.ch/chimia/article/view/2376 |