Stoichiometric Alkane and Aldehyde Hydroxylation Reactions Mediated by In Situ Generated Iron(III)-Iodosylbenzene Adduct

Stoichiometric Alkane and Aldehyde Hydroxylation Reactions Mediated by In Situ Generated Iron(III)-Iodosylbenzene Adduct

Previously synthesized and spectroscopically characterized mononuclear nonheme, low-spin iron(III)-iodosylbenzene complex bearing a bidentate pyridyl-benzimidazole ligands has been investigated in alkane and aldehyde oxidation reactions. The in situ generated Fe(III) iodosylbenzene intermediate is a...

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Bibliographic Details
Main Authors: Patrik Török, Dóra Lakk-Bogáth, József Kaizer
Format: Article
Language:English
Published: MDPI AG 2023-02-01
Series:Molecules
Subjects:
non-heme models
iron(III)–iodosylarene complex
alkane oxidation
aldehyde oxidation
C-H activation
kinetics
Online Access:https://www.mdpi.com/1420-3049/28/4/1855

Internet

https://www.mdpi.com/1420-3049/28/4/1855

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