Efficient Syntheses of Diverse N-Heterocycles: The Molybdenum(VI)-Catalyzed Reductive Cyclization of Nitroarenes using Pinacol as a Deoxygenating­ Agent

Efficient Syntheses of Diverse N-Heterocycles: The Molybdenum(VI)-Catalyzed Reductive Cyclization of Nitroarenes using Pinacol as a Deoxygenating­ Agent

Abstract Molybdenum(VI)-catalyzed domino reductive cyclization of nitroarenes has been devised for the syntheses of 1,4-benzoxazines and 1,4-benzothiazines in the presence of pinacol as deoxygenating agent. The scope of the described method was further extended to the syntheses of the rarely explore...

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Bibliographic Details
Main Authors: Raghuram Gujjarappa, Nagaraju Vodnala, Arup K. Kabi, Dhananjaya Kaldhi, Mohan Kumar, Uwe Beifuss, Chandi C. Malakar
Format: Article
Language:English
Published: Georg Thieme Verlag KG 2018-04-01
Series:SynOpen
Subjects:
n-heterocycles
domino reaction
reductive cyclization
nitro­arenes
dioxo-mo(vi) complex
pinacol
Online Access:http://www.thieme-connect.de/DOI/DOI?10.1055/s-0036-1591572

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http://www.thieme-connect.de/DOI/DOI?10.1055/s-0036-1591572

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