A novel dihydroxy nor-guaiane sesquiterpene: synthesis and crystal structure analysis

A novel dihydroxy nor-guaiane sesquiterpene: synthesis and crystal structure analysis

The epoxidation (H2O2, NaOH) of an acetonyl-cycloheptenone derived from (R)-(-)-carvone gives a dihydroxy-nor-guaiane sesquiterpene by way of an interesting sequence of reactions promoted by the basic reaction conditions. Although the major product could be identified spectroscopically with respect...

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Bibliographic Details
Main Authors: Zukerman-Schpector Julio, Caracelli Ignez, Carvalho Cristina C., Faria Mary L. de, Silva Fernando C., Matias Luiz G. de O., Brocksom Timothy J.
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2001-01-01
Series:Journal of the Brazilian Chemical Society
Subjects:
nor-guaiane sesquiterpene
epoxidation
intramolecular aldol
beta,gamma-epoxy-ketone rearrangement
X-ray analysis
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000200005

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http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000200005

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