Effect of annealing temperature on properties of SiO<sub>2</sub>/Si<sub>3</sub>N<sub>4</sub> optical films prepared by PECVD method

Based on the basic principle and algorithm of multi-layer optical thin films, SiO<sub>2</sub>/Si<sub>3</sub>N<sub>4</sub> double-layer antireflection films for three-junction reverse GaAs solar cells were prepared on GaAs substrate by plasma enhanced chemical vapo...

Full description

Bibliographic Details
Main Authors: WU Li-yu, LI Xiao-qiang, WANG Bin, QU Sheng-guan
Format: Article
Language:zho
Published: Journal of Materials Engineering 2020-12-01
Series:Cailiao gongcheng
Subjects:
Online Access:http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2019.000894
_version_ 1828078624942587904
author WU Li-yu
LI Xiao-qiang
WANG Bin
QU Sheng-guan
author_facet WU Li-yu
LI Xiao-qiang
WANG Bin
QU Sheng-guan
author_sort WU Li-yu
collection DOAJ
description Based on the basic principle and algorithm of multi-layer optical thin films, SiO<sub>2</sub>/Si<sub>3</sub>N<sub>4</sub> double-layer antireflection films for three-junction reverse GaAs solar cells were prepared on GaAs substrate by plasma enhanced chemical vapor deposition (PECVD). The relationships between post-annealing and the morphology, structure and optical properties of the multilayer films were characterized by atomic force microscope (AFM), Fourier transform infrared spectrometer (FT-IR), elliptical polarizer, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and UV-vis spectrophotometer. The results indicate that the films are crystalline state both before and after annealing. With the increase of annealing temperature, the roughness and average reflectance gradually decrease. SiO<sub>2</sub>/Si<sub>3</sub>N<sub>4</sub> films annealed at 700 ℃ have the best performance with the lowest average reflectance of 12.65% and roughness of 1.64 nm. The spectral curve of the films move towards to short-wave direction about 30 nm, showing a typical "blue-shift" phenomenon, which indicates that the optical thickness of the films demonstrates a declining trend with the rising of annealing temperature.
first_indexed 2024-04-11T02:49:43Z
format Article
id doaj.art-62e23839e1f14dda9ab9a9f326875017
institution Directory Open Access Journal
issn 1001-4381
1001-4381
language zho
last_indexed 2024-04-11T02:49:43Z
publishDate 2020-12-01
publisher Journal of Materials Engineering
record_format Article
series Cailiao gongcheng
spelling doaj.art-62e23839e1f14dda9ab9a9f3268750172023-01-02T16:33:56ZzhoJournal of Materials EngineeringCailiao gongcheng1001-43811001-43812020-12-014812758110.11868/j.issn.1001-4381.2019.00089420201209Effect of annealing temperature on properties of SiO<sub>2</sub>/Si<sub>3</sub>N<sub>4</sub> optical films prepared by PECVD methodWU Li-yu0LI Xiao-qiang1WANG Bin2QU Sheng-guan3National Engineering Research Center of Near-Net-Shape Forming for Metallic Materials, South China University of Technology, Guangzhou 510640, ChinaNational Engineering Research Center of Near-Net-Shape Forming for Metallic Materials, South China University of Technology, Guangzhou 510640, ChinaNational Engineering Research Center of Near-Net-Shape Forming for Metallic Materials, South China University of Technology, Guangzhou 510640, ChinaNational Engineering Research Center of Near-Net-Shape Forming for Metallic Materials, South China University of Technology, Guangzhou 510640, ChinaBased on the basic principle and algorithm of multi-layer optical thin films, SiO<sub>2</sub>/Si<sub>3</sub>N<sub>4</sub> double-layer antireflection films for three-junction reverse GaAs solar cells were prepared on GaAs substrate by plasma enhanced chemical vapor deposition (PECVD). The relationships between post-annealing and the morphology, structure and optical properties of the multilayer films were characterized by atomic force microscope (AFM), Fourier transform infrared spectrometer (FT-IR), elliptical polarizer, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and UV-vis spectrophotometer. The results indicate that the films are crystalline state both before and after annealing. With the increase of annealing temperature, the roughness and average reflectance gradually decrease. SiO<sub>2</sub>/Si<sub>3</sub>N<sub>4</sub> films annealed at 700 ℃ have the best performance with the lowest average reflectance of 12.65% and roughness of 1.64 nm. The spectral curve of the films move towards to short-wave direction about 30 nm, showing a typical "blue-shift" phenomenon, which indicates that the optical thickness of the films demonstrates a declining trend with the rising of annealing temperature.http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2019.000894antireflection filmgaas-based solar cellplasma enhanced chemical vapor depositionannealing
spellingShingle WU Li-yu
LI Xiao-qiang
WANG Bin
QU Sheng-guan
Effect of annealing temperature on properties of SiO<sub>2</sub>/Si<sub>3</sub>N<sub>4</sub> optical films prepared by PECVD method
Cailiao gongcheng
antireflection film
gaas-based solar cell
plasma enhanced chemical vapor deposition
annealing
title Effect of annealing temperature on properties of SiO<sub>2</sub>/Si<sub>3</sub>N<sub>4</sub> optical films prepared by PECVD method
title_full Effect of annealing temperature on properties of SiO<sub>2</sub>/Si<sub>3</sub>N<sub>4</sub> optical films prepared by PECVD method
title_fullStr Effect of annealing temperature on properties of SiO<sub>2</sub>/Si<sub>3</sub>N<sub>4</sub> optical films prepared by PECVD method
title_full_unstemmed Effect of annealing temperature on properties of SiO<sub>2</sub>/Si<sub>3</sub>N<sub>4</sub> optical films prepared by PECVD method
title_short Effect of annealing temperature on properties of SiO<sub>2</sub>/Si<sub>3</sub>N<sub>4</sub> optical films prepared by PECVD method
title_sort effect of annealing temperature on properties of sio sub 2 sub si sub 3 sub n sub 4 sub optical films prepared by pecvd method
topic antireflection film
gaas-based solar cell
plasma enhanced chemical vapor deposition
annealing
url http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2019.000894
work_keys_str_mv AT wuliyu effectofannealingtemperatureonpropertiesofsiosub2subsisub3subnsub4subopticalfilmspreparedbypecvdmethod
AT lixiaoqiang effectofannealingtemperatureonpropertiesofsiosub2subsisub3subnsub4subopticalfilmspreparedbypecvdmethod
AT wangbin effectofannealingtemperatureonpropertiesofsiosub2subsisub3subnsub4subopticalfilmspreparedbypecvdmethod
AT qushengguan effectofannealingtemperatureonpropertiesofsiosub2subsisub3subnsub4subopticalfilmspreparedbypecvdmethod