Facile Access to Stable Silylium Ions Stabilized by N-Heterocyclic Imines

Facile Access to Stable Silylium Ions Stabilized by N-Heterocyclic Imines

Novel silylium ions with N-heterocyclic imines were successfully synthesized. The reaction of trimethylsilyl imidazolin-2-imine Me3SiNIPr (NIPr = bis(2,6-diisopropylphenyl)-imidazolin-2-imino) with B(C6F5)3 leads to dimeric imino-substituted silylium ions through a methyl group abstraction on the si...

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Bibliographic Details
Main Authors: Tatsumi Ochiai, Tibor Szilvási, Shigeyoshi Inoue
Format: Article
Language:English
Published: MDPI AG 2016-08-01
Series:Molecules
Subjects:
silylium
imine
cation
silicon
borate
Online Access:http://www.mdpi.com/1420-3049/21/9/1155

Internet

http://www.mdpi.com/1420-3049/21/9/1155

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