Unexpected Decarbonylation of Acylethynylpyrroles under the Action of Cyanomethyl Carbanion: A Robust Access to Ethynylpyrroles
It has been found that the addition of CH<sub>2</sub>CN<sup>−</sup> anion to the carbonyl group of acylethynylpyrroles, generated from acetonitrile and <i>t</i>-BuOK, results in the formation of acetylenic alcohols, which undergo unexpectedly easy (room temperatur...
| Auteurs principaux: | , , , , , |
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| Format: | Article |
| Langue: | English |
| Publié: |
MDPI AG
2023-02-01
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| Collection: | Molecules |
| Sujets: | |
| Accès en ligne: | https://www.mdpi.com/1420-3049/28/3/1389 |