Unexpected Decarbonylation of Acylethynylpyrroles under the Action of Cyanomethyl Carbanion: A Robust Access to Ethynylpyrroles

It has been found that the addition of CH<sub>2</sub>CN<sup>−</sup> anion to the carbonyl group of acylethynylpyrroles, generated from acetonitrile and <i>t</i>-BuOK, results in the formation of acetylenic alcohols, which undergo unexpectedly easy (room temperatur...

وصف كامل

التفاصيل البيبلوغرافية
المؤلفون الرئيسيون: Denis N. Tomilin, Lyubov N. Sobenina, Alexandra M. Belogolova, Alexander B. Trofimov, Igor A. Ushakov, Boris A. Trofimov
التنسيق: مقال
اللغة:English
منشور في: MDPI AG 2023-02-01
سلاسل:Molecules
الموضوعات:
الوصول للمادة أونلاين:https://www.mdpi.com/1420-3049/28/3/1389