Unexpected Decarbonylation of Acylethynylpyrroles under the Action of Cyanomethyl Carbanion: A Robust Access to Ethynylpyrroles
It has been found that the addition of CH<sub>2</sub>CN<sup>−</sup> anion to the carbonyl group of acylethynylpyrroles, generated from acetonitrile and <i>t</i>-BuOK, results in the formation of acetylenic alcohols, which undergo unexpectedly easy (room temperatur...
المؤلفون الرئيسيون: | , , , , , |
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التنسيق: | مقال |
اللغة: | English |
منشور في: |
MDPI AG
2023-02-01
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سلاسل: | Molecules |
الموضوعات: | |
الوصول للمادة أونلاين: | https://www.mdpi.com/1420-3049/28/3/1389 |