Crystallisation in Melts of Short, Semi-Flexible Hard-Sphere Polymer Chains: The Role of the Non-Bonded Interaction Range
A melt of short semi-flexible polymers with hard-sphere-type non-bonded interaction undergoes a first-order crystallisation transition at lower density than a melt of hard-sphere monomers or a flexible hard-sphere chain. In contrast to the flexible hard-sphere chains, the semi-flexible ones have an...
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| Format: | Article |
| Language: | English |
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MDPI AG
2019-09-01
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| Series: | Entropy |
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| Online Access: | https://www.mdpi.com/1099-4300/21/9/856 |