Mutual Placement of Isocyanide and Phosphine Ligands in Platinum(II) Complexes [PtHal<sub>2</sub>L<sup>1</sup>L<sup>2</sup>] (Hal = Cl, Br, I; L<sup>1</sup>,L<sup>2</sup> = CNCy, PPh<sub>3</sub>) Leads to Highly-Efficient Photocatalysts for Hydrosilylation of Alkynes

Mutual Placement of Isocyanide and Phosphine Ligands in Platinum(II) Complexes [PtHal<sub>2</sub>L<sup>1</sup>L<sup>2</sup>] (Hal = Cl, Br, I; L<sup>1</sup>,L<sup>2</sup> = CNCy, PPh<sub>3</sub>) Leads to Highly-Efficient Photocatalysts for Hydrosilylation of Alkynes

A series of platinum complexes featuring phosphine and isocyanide ligands [PtX<sub>2</sub>(PPh<sub>3</sub>)(CNCy)] (X = Cl, Br, and I) as well as their parent phosphine [PtX<sub>2</sub>(PPh<sub>3</sub>)<sub>2</sub>] and isocyanide [PtX<s...

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Bibliographic Details
Main Authors: Maria V. Kashina, Andrei A. Karcheuski, Mikhail A. Kinzhalov, Konstantin V. Luzyanin, Svetlana A. Katkova
Format: Article
Language:English
Published: MDPI AG 2023-11-01
Series:Molecules
Subjects:
isocyanide ligands
platinum(II) complexes
catalytic activity
hydrosilylation
photocatalysis
Online Access:https://www.mdpi.com/1420-3049/28/23/7764

Internet

https://www.mdpi.com/1420-3049/28/23/7764

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