Catalytic cycloaddition of acrylates to norbornadiene. Kinetics and mechanism
Kinetics of [2+2+2]-cycloaddition of acrylates to norbornadiene in the presence of η3-bis(allyl) nickel was studied. The thermodynamic parameters were determined. Kinetics equations for all of the isomer reaction products were found. The data obtained agree with the formerly proposed mechanism.
| Main Authors: | , , , |
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| Format: | Article |
| Language: | Russian |
| Published: |
MIREA - Russian Technological University
2010-10-01
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| Series: | Тонкие химические технологии |
| Subjects: | |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/932 |