Bromidocarbonyl{(1S,2S)-N-[2-(dicyclohexylphosphanyl)ethylidenyl]-N′-[2-(diphenylphosphanyl)ethyl]-1,2-diphenylethane-1,2-diamine}iron(II) tetraphenylborate

Bromidocarbonyl{(1S,2S)-N-[2-(dicyclohexylphosphanyl)ethylidenyl]-N′-[2-(diphenylphosphanyl)ethyl]-1,2-diphenylethane-1,2-diamine}iron(II) tetraphenylborate

In the title compound, trans-(S,S)-[FeBr(CO)(PPh2CH2CH2NHCHPhCHPhNCHCH2PCy2)]BPh4, the FeII ion is in a distorted octahedral complex geometry with a cis-β ligand geometry in which two diastereomers co-crystallized in the asymmetric unit. These diastereomers differ by the orientation of the N—H moiet...

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Bibliographic Details
Main Authors: Samantha A. M. Smith, Alan J. Lough, Robert H. Morris
Format: Article
Language:English
Published: International Union of Crystallography 2017-03-01
Series:IUCrData
Subjects:
crystal structure
diastereomers
cis-β ligand geometry
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314617004527

Internet

http://scripts.iucr.org/cgi-bin/paper?S2414314617004527

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