Synthesis and crystal structure of decacarbonyl(μ3-3,7-dithianonane-1,9-dithiolato)bis(μ2-propane-1,3-dithiolato)nickel(II)tetrairon(II) dichloromethane disolvate

Synthesis and crystal structure of decacarbonyl(μ3-3,7-dithianonane-1,9-dithiolato)bis(μ2-propane-1,3-dithiolato)nickel(II)tetrairon(II) dichloromethane disolvate

The title compound,, [Fe4Ni(C3H6S2)2(C7H14S4)(CO)10]·2CH2Cl2, is reported as a biomimic model for the active site of [FeFe]-hydrogenases. Bis(2-mercaptoethyl)-1,3-propanedithio ether nickel(II) was firstly introduced into [Fe2(C3H6S2)(CO)5] as an S-containing ligand. It coordinates with two [Fe2(C3H...

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Bibliographic Details
Main Authors: Gan Ren, Ge Sang
Format: Article
Language:English
Published: International Union of Crystallography 2018-03-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
FeS
catalysis
proton reduction
electrochemistry
H-cluster
[FeFe]-hydrogenase
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018001731

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http://scripts.iucr.org/cgi-bin/paper?S2056989018001731

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