Generation of Mixed Anhydrides via Oxidative Fragmentation of Tertiary Cyclopropanols with Phenyliodine(III) Dicarboxylates

Generation of Mixed Anhydrides via Oxidative Fragmentation of Tertiary Cyclopropanols with Phenyliodine(III) Dicarboxylates

Oxidative fragmentation of tertiary cyclopropanols with phenyliodine(III) dicarboxylates in aprotic solvents (dichloromethane, chloroform, toluene) produces mixed anhydrides. The fragmentation reaction is especially facile with phenyliodine(III) reagents bearing electron-withdrawing carboxylate liga...

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Bibliographic Details
Main Authors: Dzmitry M. Zubrytski, Gábor Zoltán Elek, Margus Lopp, Dzmitry G. Kananovich
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Molecules
Subjects:
cyclopropanols
mixed anhydrides
amides
macrolactonization
hypervalent iodine reagents
acylation
Online Access:https://www.mdpi.com/1420-3049/26/1/140

Internet

https://www.mdpi.com/1420-3049/26/1/140

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