Crystal structure of [Co(NH3)6][Co(CO)4]2

Crystal structure of [Co(NH3)6][Co(CO)4]2

Hexaamminecobalt(II) bis[tetracarbonylcobaltate(-I)], [Co(NH3)6][Co(CO)4]2, was synthesized by reaction of liquid ammonia with Co2(CO)8. The CoII atom is coordinated by six ammine ligands. The resulting polyhedron, the hexaamminecobalt(II) cation, exhibits point group symmetry -3. The Co-I atom is c...

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Bibliographic Details
Main Authors: Thomas G. Müller, Florian Kraus
Format: Article
Language:English
Published: International Union of Crystallography 2015-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
cobalt carbonyl
ammonia
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015020290

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http://scripts.iucr.org/cgi-bin/paper?S2056989015020290

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