Photoluminescence Spectral Patterns and Parameters of Milk While Souring

For the efficient production and processing of milk, it is important to control its quality indicators. Optical spectroscopy, in combination with statistical analysis methods, can be a useful method of evaluation due to its speed, non-invasiveness, and relative cheapness. This investigation is aimed...

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Main Authors: Mikhail V. Belyakov, Gennady N. Samarin, Vyacheslav A. Ruzhev, Alexander A. Kudryavtsev, Igor Yu. Efremenkov, Nikita D. Blinov
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Agriculture
Subjects:
Online Access:https://www.mdpi.com/2077-0472/13/5/1054
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author Mikhail V. Belyakov
Gennady N. Samarin
Vyacheslav A. Ruzhev
Alexander A. Kudryavtsev
Igor Yu. Efremenkov
Nikita D. Blinov
author_facet Mikhail V. Belyakov
Gennady N. Samarin
Vyacheslav A. Ruzhev
Alexander A. Kudryavtsev
Igor Yu. Efremenkov
Nikita D. Blinov
author_sort Mikhail V. Belyakov
collection DOAJ
description For the efficient production and processing of milk, it is important to control its quality indicators. Optical spectroscopy, in combination with statistical analysis methods, can be a useful method of evaluation due to its speed, non-invasiveness, and relative cheapness. This investigation is aimed at studying of the interrelations of the spectral patterns, the absorption parameters, and the photoluminescence values of cow’s milk during its souring. The spectral characteristics of excitation and photoluminescence were measured on a diffraction spectrofluorometer in the range of 200–500 nm. For establishing an effective control procedure during milk souring, the most informative method is found to be the use of the excitation wavelengths of 232 nm, 322 nm, 385 nm and 442 nm. These ranges correspond to the amino acids of milk proteins, the fatty acids of milk fat, and the aromatic fragments of vitamins. When using the photoluminescence flux ratios Φ<sub>232</sub>/Φ<sub>322</sub> and Φ<sub>385</sub>/Φ<sub>442</sub>, linearly approximated dependences on acidity can be obtained with determination coefficients of 0.88–0.94. The proposed photoluminescent method can be used as a non-destructive and fast-acting tool for monitoring the properties of milk during fermentation, as well as for the subsequent creation of a portable and inexpensive sensor based on this method.
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spelling doaj.art-6972d11669b14124a36eecb7652310072023-11-18T00:03:18ZengMDPI AGAgriculture2077-04722023-05-01135105410.3390/agriculture13051054Photoluminescence Spectral Patterns and Parameters of Milk While SouringMikhail V. Belyakov0Gennady N. Samarin1Vyacheslav A. Ruzhev2Alexander A. Kudryavtsev3Igor Yu. Efremenkov4Nikita D. Blinov5Laboratory of Agricultural Products Processing, Federal Scientific Agroengineering Center VIM, 109428 Moscow, RussiaLaboratory of Agricultural Products Processing, Federal Scientific Agroengineering Center VIM, 109428 Moscow, RussiaDepartment of Technical Systems in Agribusiness, St. Petersburg State Agrarian University, 196601 Saint-Petersburg, RussiaLaboratory of Agricultural Products Processing, Federal Scientific Agroengineering Center VIM, 109428 Moscow, RussiaLaboratory of Agricultural Products Processing, Federal Scientific Agroengineering Center VIM, 109428 Moscow, RussiaLaboratory of Agricultural Products Processing, Federal Scientific Agroengineering Center VIM, 109428 Moscow, RussiaFor the efficient production and processing of milk, it is important to control its quality indicators. Optical spectroscopy, in combination with statistical analysis methods, can be a useful method of evaluation due to its speed, non-invasiveness, and relative cheapness. This investigation is aimed at studying of the interrelations of the spectral patterns, the absorption parameters, and the photoluminescence values of cow’s milk during its souring. The spectral characteristics of excitation and photoluminescence were measured on a diffraction spectrofluorometer in the range of 200–500 nm. For establishing an effective control procedure during milk souring, the most informative method is found to be the use of the excitation wavelengths of 232 nm, 322 nm, 385 nm and 442 nm. These ranges correspond to the amino acids of milk proteins, the fatty acids of milk fat, and the aromatic fragments of vitamins. When using the photoluminescence flux ratios Φ<sub>232</sub>/Φ<sub>322</sub> and Φ<sub>385</sub>/Φ<sub>442</sub>, linearly approximated dependences on acidity can be obtained with determination coefficients of 0.88–0.94. The proposed photoluminescent method can be used as a non-destructive and fast-acting tool for monitoring the properties of milk during fermentation, as well as for the subsequent creation of a portable and inexpensive sensor based on this method.https://www.mdpi.com/2077-0472/13/5/1054cow’s milksouringphotoluminescent analysisUV-Vis rangelinear regression models
spellingShingle Mikhail V. Belyakov
Gennady N. Samarin
Vyacheslav A. Ruzhev
Alexander A. Kudryavtsev
Igor Yu. Efremenkov
Nikita D. Blinov
Photoluminescence Spectral Patterns and Parameters of Milk While Souring
Agriculture
cow’s milk
souring
photoluminescent analysis
UV-Vis range
linear regression models
title Photoluminescence Spectral Patterns and Parameters of Milk While Souring
title_full Photoluminescence Spectral Patterns and Parameters of Milk While Souring
title_fullStr Photoluminescence Spectral Patterns and Parameters of Milk While Souring
title_full_unstemmed Photoluminescence Spectral Patterns and Parameters of Milk While Souring
title_short Photoluminescence Spectral Patterns and Parameters of Milk While Souring
title_sort photoluminescence spectral patterns and parameters of milk while souring
topic cow’s milk
souring
photoluminescent analysis
UV-Vis range
linear regression models
url https://www.mdpi.com/2077-0472/13/5/1054
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