Simple, near-universal relationships between bond lengths, strengths, and anharmonicities
Harmonic bond force constants and bond lengths are shown to generally obey the simple relationships, ke=ζ2Re−3 (hydrides) and ke=10ζ1/2Re−4 (all other bond types), where ζ is the reduced nuclear charge and Re is the equilibrium bond length. Equally simple power-law relationships are found for higher...
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| Format: | Article |
| Language: | English |
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AIP Publishing LLC
2023-11-01
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| Series: | AIP Advances |
| Online Access: | http://dx.doi.org/10.1063/5.0175455 |