Direct C2–H alkylation of indoles driven by the photochemical activity of halogen-bonded complexes

Direct C2–H alkylation of indoles driven by the photochemical activity of halogen-bonded complexes

A light-driven metal-free protocol for the synthesis of sulfone-containing indoles under mild conditions is reported. Specifically, the process is driven by the photochemical activity of halogen-bonded complexes formed upon complexation of a sacrificial donor, namely 1,4-diazabicyclo[2.2.2]octane (D...

Full description

Bibliographic Details
Main Authors: Martina Mamone, Giuseppe Gentile, Jacopo Dosso, Maurizio Prato, Giacomo Filippini
Format: Article
Language:English
Published: Beilstein-Institut 2023-04-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
alkylation
eda complex
halogens
indoles
photochemistry
Online Access:https://doi.org/10.3762/bjoc.19.42

Internet

https://doi.org/10.3762/bjoc.19.42

Similar Items