Crystal structure of tricarbonyl(μ-diphenylphosphido-κ2P:P)(methyldiphenylsilyl-κSi)bis(triphenylphosphane-κP)iron(II)platinum(0)(Fe—Pt)

Crystal structure of tricarbonyl(μ-diphenylphosphido-κ2P:P)(methyldiphenylsilyl-κSi)bis(triphenylphosphane-κP)iron(II)platinum(0)(Fe—Pt)

The title compound, [FePt(C12H10P)(C13H13Si)(C18H15P)2(CO)3]·0.5CH2Cl2, represents an example of a phosphido-bridged heterobimetallic silyl complex; these are interesting precursors for the coordination and activation of small unsaturated organic molecules. The μ2-PPh2 ligand spans the iron and plat...

Full description

Bibliographic Details
Main Authors: Ahmed Said Mohamed, Isabelle Jourdain, Michael Knorr, Yoann Rousselin, Marek M. Kubicki
Format: Article
Language:English
Published: International Union of Crystallography 2015-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
heterobimetallics
phosphido bridges
iron complexes
platinum complexes
diphenylmethylsilyl ligand
metal–metal bond
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015001565

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989015001565

Similar Items