Two New Rb<sub>3</sub>Sc(IO<sub>3</sub>)<sub>6</sub> Polytypes in Proposed Nonlinear Optical Family A<sub>3</sub>M(IO<sub>3</sub>)<sub>6</sub> (A = K, Rb; M = Sc, In): Topology–Symmetry Analysis, Order–Disorder and Structure–Properties Relation

Two New Rb<sub>3</sub>Sc(IO<sub>3</sub>)<sub>6</sub> Polytypes in Proposed Nonlinear Optical Family A<sub>3</sub>M(IO<sub>3</sub>)<sub>6</sub> (A = K, Rb; M = Sc, In): Topology–Symmetry Analysis, Order–Disorder and Structure–Properties Relation

Two polytypic modifications of new non-centrosymmetric iodate Rb<sub>3</sub>Sc(IO<sub>3</sub>)<sub>6</sub> are synthesized hydrothermally. Their structures demonstrate different degrees of ordering and are solved in the same space group, <i>Pc</i>, wit...

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Bibliographic Details
Main Authors: Olga Reutova, Elena Belokoneva, Anatoly Volkov, Olga Dimitrova, Sergey Stefanovich
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Symmetry
Subjects:
iodates
hydrothermal synthesis
single-crystal X-ray diffraction
nonlinear optical properties
topology–symmetry analysis
order–disorder
Online Access:https://www.mdpi.com/2073-8994/14/8/1699

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https://www.mdpi.com/2073-8994/14/8/1699

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