Single-Crystal to Single-Crystal Reversible Transformations Induced by Thermal Dehydration in Keggin-Type Polyoxometalates Decorated with Copper(II)-Picolinate Complexes: The Structure Directing Role of Guanidinium

Single-Crystal to Single-Crystal Reversible Transformations Induced by Thermal Dehydration in Keggin-Type Polyoxometalates Decorated with Copper(II)-Picolinate Complexes: The Structure Directing Role of Guanidinium

Three new hybrid inorganic-metalorganic compounds containing Keggin-type polyoxometalates, neutral copper(II)-picolinate complexes and guanidinium cations have been synthesized in bench conditions and characterized by elemental analysis, infrared spectroscopy and single-crystal X-ray diffraction:...

Full description

Bibliographic Details
Main Authors: Aroa Pache, Santiago Reinoso, Leire San Felices, Amaia Iturrospe, Luis Lezama, Juan M. Gutiérrez-Zorrilla
Format: Article
Language:English
Published: MDPI AG 2015-05-01
Series:Inorganics
Subjects:
polyoxometalates
crystal-to-crystal transformations
guanidinium
Online Access:http://www.mdpi.com/2304-6740/3/2/194

Internet

http://www.mdpi.com/2304-6740/3/2/194

Similar Items