Radical Cross Coupling and Enantioselective Protonation through Asymmetric Photoredox Catalysis

Radical Cross Coupling and Enantioselective Protonation through Asymmetric Photoredox Catalysis

Abstract An unprecedented enantioselective protonation reaction enabled by photoredox catalytic radical coupling is developed. Under cooperative dicynopyrazine‐derived chromophore (DPZ) as a photosensitizer and a chiral phosphoric acid catalyst, and Hantzsch ester as a sacrificial reductant, the tra...

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Bibliographic Details
Main Authors: Manman Kong, Zhuoxi Wang, Xu Ban, Xiaowei Zhao, Yanli Yin, Junmin Zhang, Zhiyong Jiang
Format: Article
Language:English
Published: Wiley 2024-03-01
Series:Advanced Science
Subjects:
asymmetric catalysis
azaarenes
enantioselective protonation
photoredox catalysis
radical coupling
Online Access:https://doi.org/10.1002/advs.202307773

Internet

https://doi.org/10.1002/advs.202307773

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