A new type of C+⋯Hδ−(C=) bond in adducts of vinyl carbocations with alkenes
Abstract By X-ray diffraction analysis and IR spectroscopy, it was established here that vinyl carbocations C3H5 +/C4H7 + with carborane counterion CHB11Cl11 − form stable monosolvates C3H5 +⋅C3H6/C4H7 +⋅C4H8 with molecules of alkenes C3H6/C4H8. They contain molecular group =C+⋯Hδ−–Cδ+= with a new t...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2024-04-01
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| Series: | Scientific Reports |
| Online Access: | https://doi.org/10.1038/s41598-024-58109-4 |