Enantiopure Cyclometalated Rh(III) and Ir(III) Complexes Displaying Rigid Configuration at Metal Center: Design, Structures, Chiroptical Properties and Role of the Iodide Ligand

Enantiopure Cyclometalated Rh(III) and Ir(III) Complexes Displaying Rigid Configuration at Metal Center: Design, Structures, Chiroptical Properties and Role of the Iodide Ligand

Enantiopure <i>N</i>-heterocyclic carbene half-sandwich metal complexes of the general formula [Cp*M(C^C:)I] (M = Rh, Ir; C^C: = NI-NHC; NI-H = Naphthalimide; NHC = <i>N</i>-heterocyclic carbene) are reported. The rhodium compound was obtained as a single isomer displaying si...

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Bibliographic Details
Main Authors: Antoine Groué, Jean-Philippe Tranchier, Geoffrey Gontard, Marion Jean, Nicolas Vanthuyne, Hani Amouri
Format: Article
Language:English
Published: MDPI AG 2022-03-01
Series:Chemistry
Subjects:
chiral resolution
enantiopure
configurational stability
circular dichroism
Online Access:https://www.mdpi.com/2624-8549/4/1/14

Internet

https://www.mdpi.com/2624-8549/4/1/14

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