Electron-beam radiation induced degradation of silicon nitride and its impact to semiconductor failure analysis by TEM

By in-situ transmission electron microscopy (TEM), we performed a detailed study on the electron-beam radiation damage to nanostructured silicon nitride thin-film process layers in a typical semiconductor NVM device. It was found that high-dose electron-beam radiation at 200 kV led to rapid degradat...

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Main Authors: Binghai Liu, Zhi Li Dong, Younan Hua, Chao Fu, Xiaomin Li, Pik Kee Tan, Yuzhe Zhao
Format: Article
Language:English
Published: AIP Publishing LLC 2018-11-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.5051813
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author Binghai Liu
Zhi Li Dong
Younan Hua
Chao Fu
Xiaomin Li
Pik Kee Tan
Yuzhe Zhao
author_facet Binghai Liu
Zhi Li Dong
Younan Hua
Chao Fu
Xiaomin Li
Pik Kee Tan
Yuzhe Zhao
author_sort Binghai Liu
collection DOAJ
description By in-situ transmission electron microscopy (TEM), we performed a detailed study on the electron-beam radiation damage to nanostructured silicon nitride thin-film process layers in a typical semiconductor NVM device. It was found that high-dose electron-beam radiation at 200 kV led to rapid degradation of silicon nitride process layers, i.e. thin-downing of nanostructured silicon nitride, inter-diffusion of O and N, the formation of bubble-like defects and segregation of N at neighbouring interfaces. Further detailed analysis revealed that radiation-induced modification in the microstructure and chemical composition of silicon nitride layers could be ascribed to the electron radiation induced knock-on damage and ionization damage. The radiation enhanced diffusion (RED) accounted for the continuous thin-down of the nitride process layer and the formation of bubble-like defects in thick nitride spacer process layers. The work well demonstrated the electron-beam sensitivity of nanostructured silicon nitride materials in the semiconductor devices, and thus may give useful information about electron-dose control during TEM failure analysis of the semiconductor devices containing nanostructured silicon nitride process layers.
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spelling doaj.art-6f56e835d12142789c42c12c8151ced42022-12-22T01:02:05ZengAIP Publishing LLCAIP Advances2158-32262018-11-01811115327115327-1110.1063/1.5051813098811ADVElectron-beam radiation induced degradation of silicon nitride and its impact to semiconductor failure analysis by TEMBinghai Liu0Zhi Li Dong1Younan Hua2Chao Fu3Xiaomin Li4Pik Kee Tan5Yuzhe Zhao6Wintech Nano-Technology Service Pte Ltd, 117684, SingaporeSchool of Materials Science & Engineering, College of Engineering, Nangyang Technologic University, 639798, SingaporeWintech Nano-Technology Service Pte Ltd, 117684, SingaporeWintech Nano-Technology Service Pte Ltd, 117684, SingaporeWintech Nano-Technology Service Pte Ltd, 117684, SingaporeDepartment of Product, Test and Failure Analysis, Globalfoundries Singapore Pte Ltd, 738406, SingaporeDepartment of Product, Test and Failure Analysis, Globalfoundries Singapore Pte Ltd, 738406, SingaporeBy in-situ transmission electron microscopy (TEM), we performed a detailed study on the electron-beam radiation damage to nanostructured silicon nitride thin-film process layers in a typical semiconductor NVM device. It was found that high-dose electron-beam radiation at 200 kV led to rapid degradation of silicon nitride process layers, i.e. thin-downing of nanostructured silicon nitride, inter-diffusion of O and N, the formation of bubble-like defects and segregation of N at neighbouring interfaces. Further detailed analysis revealed that radiation-induced modification in the microstructure and chemical composition of silicon nitride layers could be ascribed to the electron radiation induced knock-on damage and ionization damage. The radiation enhanced diffusion (RED) accounted for the continuous thin-down of the nitride process layer and the formation of bubble-like defects in thick nitride spacer process layers. The work well demonstrated the electron-beam sensitivity of nanostructured silicon nitride materials in the semiconductor devices, and thus may give useful information about electron-dose control during TEM failure analysis of the semiconductor devices containing nanostructured silicon nitride process layers.http://dx.doi.org/10.1063/1.5051813
spellingShingle Binghai Liu
Zhi Li Dong
Younan Hua
Chao Fu
Xiaomin Li
Pik Kee Tan
Yuzhe Zhao
Electron-beam radiation induced degradation of silicon nitride and its impact to semiconductor failure analysis by TEM
AIP Advances
title Electron-beam radiation induced degradation of silicon nitride and its impact to semiconductor failure analysis by TEM
title_full Electron-beam radiation induced degradation of silicon nitride and its impact to semiconductor failure analysis by TEM
title_fullStr Electron-beam radiation induced degradation of silicon nitride and its impact to semiconductor failure analysis by TEM
title_full_unstemmed Electron-beam radiation induced degradation of silicon nitride and its impact to semiconductor failure analysis by TEM
title_short Electron-beam radiation induced degradation of silicon nitride and its impact to semiconductor failure analysis by TEM
title_sort electron beam radiation induced degradation of silicon nitride and its impact to semiconductor failure analysis by tem
url http://dx.doi.org/10.1063/1.5051813
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