Interfacial layer assisted, forming free, and reliable bipolar resistive switching in solution processed BiFeO3 thin films

BiFeO3 based resistive random access memory (RRAM) devices are fabricated using a low-cost solution process to study the effect of an Al top electrode on switching behavior and reliability. Fabricated devices demonstrated bipolar switching characteristics with a moderate Ion/Ioff ratio, set and rese...

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Main Authors: Chandni Kumari, Ishan Varun, Shree Prakash Tiwari, Ambesh Dixit
Format: Article
Language:English
Published: AIP Publishing LLC 2020-02-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.5134972
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author Chandni Kumari
Ishan Varun
Shree Prakash Tiwari
Ambesh Dixit
author_facet Chandni Kumari
Ishan Varun
Shree Prakash Tiwari
Ambesh Dixit
author_sort Chandni Kumari
collection DOAJ
description BiFeO3 based resistive random access memory (RRAM) devices are fabricated using a low-cost solution process to study the effect of an Al top electrode on switching behavior and reliability. Fabricated devices demonstrated bipolar switching characteristics with a moderate Ion/Ioff ratio, set and reset voltages of ∼−1.3 V and ∼0.8 V, DC and AC endurance of more than 250 cycles and 7100 cycles, respectively, and a retention time of over 104 s, confirming the non-volatile resistive switching behavior. The ohmic and trap filled space charge limited conduction dominates the conduction mechanism in the devices at lower and higher voltages, respectively. Moreover, impedance spectroscopy measurements substantiate the presence of an AlOx layer at the Al/BiFeO3 interface resulting from the Al–O interaction at the junction, which is the possible rationale of reliable complementary switching in these RRAM devices. The switching mechanism is elucidated using the formation and rupture of the oxygen vacancy mediated filament, assisted by the participation of a thin AlOx layer at the Al/BFO interface. The role of the thin AlOx layer is explained by modeling of impedances.
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spelling doaj.art-6fa7153500ee49f2a4d981ca892a7eda2022-12-21T22:41:44ZengAIP Publishing LLCAIP Advances2158-32262020-02-01102025110025110-710.1063/1.5134972Interfacial layer assisted, forming free, and reliable bipolar resistive switching in solution processed BiFeO3 thin filmsChandni Kumari0Ishan Varun1Shree Prakash Tiwari2Ambesh Dixit3Department of Physics, Indian Institute of Technology Jodhpur, Rajasthan 342037, IndiaDepartment of Electrical Engineering, Indian Institute of Technology Jodhpur, Rajasthan 342037, IndiaDepartment of Electrical Engineering, Indian Institute of Technology Jodhpur, Rajasthan 342037, IndiaDepartment of Physics, Indian Institute of Technology Jodhpur, Rajasthan 342037, IndiaBiFeO3 based resistive random access memory (RRAM) devices are fabricated using a low-cost solution process to study the effect of an Al top electrode on switching behavior and reliability. Fabricated devices demonstrated bipolar switching characteristics with a moderate Ion/Ioff ratio, set and reset voltages of ∼−1.3 V and ∼0.8 V, DC and AC endurance of more than 250 cycles and 7100 cycles, respectively, and a retention time of over 104 s, confirming the non-volatile resistive switching behavior. The ohmic and trap filled space charge limited conduction dominates the conduction mechanism in the devices at lower and higher voltages, respectively. Moreover, impedance spectroscopy measurements substantiate the presence of an AlOx layer at the Al/BiFeO3 interface resulting from the Al–O interaction at the junction, which is the possible rationale of reliable complementary switching in these RRAM devices. The switching mechanism is elucidated using the formation and rupture of the oxygen vacancy mediated filament, assisted by the participation of a thin AlOx layer at the Al/BFO interface. The role of the thin AlOx layer is explained by modeling of impedances.http://dx.doi.org/10.1063/1.5134972
spellingShingle Chandni Kumari
Ishan Varun
Shree Prakash Tiwari
Ambesh Dixit
Interfacial layer assisted, forming free, and reliable bipolar resistive switching in solution processed BiFeO3 thin films
AIP Advances
title Interfacial layer assisted, forming free, and reliable bipolar resistive switching in solution processed BiFeO3 thin films
title_full Interfacial layer assisted, forming free, and reliable bipolar resistive switching in solution processed BiFeO3 thin films
title_fullStr Interfacial layer assisted, forming free, and reliable bipolar resistive switching in solution processed BiFeO3 thin films
title_full_unstemmed Interfacial layer assisted, forming free, and reliable bipolar resistive switching in solution processed BiFeO3 thin films
title_short Interfacial layer assisted, forming free, and reliable bipolar resistive switching in solution processed BiFeO3 thin films
title_sort interfacial layer assisted forming free and reliable bipolar resistive switching in solution processed bifeo3 thin films
url http://dx.doi.org/10.1063/1.5134972
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