Crystal structure of di-μ-methanolato-bis{[N′-(1-benzoylprop-1-en-2-yl)thiophene-2-carbohydrazidato-κ3O,N′,O′]oxidovanadium(V)}

Crystal structure of di-μ-methanolato-bis{[N′-(1-benzoylprop-1-en-2-yl)thiophene-2-carbohydrazidato-κ3O,N′,O′]oxidovanadium(V)}

The neutral binuclear molecule of the title complex, [V2(C15H12N2O2S)2(CH3O)2O2], exhibits inversion symmetry and consists of two oxidovanadium(V) (VO)3+ fragments, each coordinated by a dianionic and O,N′,O′-chelating N′-(1-benzoylprop-1-en-2-yl)thiophene-2-carbohydrazidate ligand. The V5+ cations...

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Bibliographic Details
Main Authors: Murilo C. Carroccia, Rafaela B. P. Pesci, Pedro Ivo da S. Maia, Victor M. Deflon
Format: Article
Language:English
Published: International Union of Crystallography 2014-10-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
thiophene-2-carbohydrazide
vanadium(V) complex
dinuclear complex
alkoxide bridging
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814020327

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http://scripts.iucr.org/cgi-bin/paper?S1600536814020327

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