Synthesis and crystal structure of 2-(anthracen-9-yl)-1-(tert-butyldimethylsilyl)-3,6-dihydro-1λ4,2λ4-azaborinine

Synthesis and crystal structure of 2-(anthracen-9-yl)-1-(tert-butyldimethylsilyl)-3,6-dihydro-1λ4,2λ4-azaborinine

The title compound, C24H30BNSi (I), is an asymmetric 1,2,3,6-tetrahydro-1,2-azaborinine consisting of a BN-substituted cyclohexadiene analog with a B-anthracenyl substituent. A ring-closing metathesis with subsequent substitution of the obtained BCl 1,2-azaborinine using anthracenyl lithium yielded...

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Bibliographic Details
Main Authors: Philipp J. Gliese, Yannik Appiarius, Tarek Scheele, Enno Lork, Tim Neudecker, Anne Staubitz
Format: Article
Language:English
Published: International Union of Crystallography 2023-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
1,2-azaborinine
boron–nitrogen bond
boron–nitrogen heterocycle
ring-closing metathesis
bn cyclohexene
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989023008381

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http://scripts.iucr.org/cgi-bin/paper?S2056989023008381

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