(4R)- and (4S)-Azidoprolines – Conformation Directing Amino Acids and Sites for Functionalization

An 'azido gauche effect' determines the conformation of (4S)- and (4R)-azidoproline (Azp) derivatives and affects the s-cis:s-trans conformer ratio of Xaa-Azp bonds. The article summarizes our research on the conformational analysis of monomers as well as oligomers derived from (...

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Bibliographic Details
Main Authors: Roman S. Erdmann, Michael Kümin, Helma Wennemers
Format: Article
Language:deu
Published: Swiss Chemical Society 2009-04-01
Series:CHIMIA
Subjects:
Online Access:https://www.chimia.ch/chimia/article/view/4644