Synthesis, crystal structure and properties of chloridotetrakis(pyridine-3-carbonitrile)thiocyanatoiron(II)

Synthesis, crystal structure and properties of chloridotetrakis(pyridine-3-carbonitrile)thiocyanatoiron(II)

Reaction of FeCl2·4H2O with KSCN and 3-cyanopyridine (pyridine-3-carbonitrile) in ethanol accidentally leads to the formation of single crystals of Fe(NCS)(Cl)(3-cyanopyridine)4 or [FeCl(NCS)(C6H4N2)4]. The asymmetric unit of this compound consists of one FeII cation, one chloride and one thiocyanat...

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Bibliographic Details
Main Authors: Asmus Müller-Meinhard, Inke Jess, Christian Näther
Format: Article
Language:English
Published: International Union of Crystallography 2023-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
synthesis
crystal structure
mixed iron thiocyanate chloride complex
powder diffraction
thermal properties
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698902300988X

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http://scripts.iucr.org/cgi-bin/paper?S205698902300988X

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