On the Conundrum of the Heat Capacityof Metallic Nanoclasters
The heat capacity of nanoclusters was investigated using thermodynamics of surfaces, taking into account the surface enthalpy introduced by E. Guggenhein. It is shown that the cluster heat capacity Cp should be greater than the heat capacity C(b)p of the corresponding bulk phase. However, the (Cp -...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
al-Farabi Kazakh National University
2012-11-01
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Series: | Eurasian Chemico-Technological Journal |
Online Access: | http://ect-journal.kz/index.php/ectj/article/view/413 |