Aldiminium and 1,2,3-triazolium dithiocarboxylate zwitterions derived from cyclic (alkyl)(amino) and mesoionic carbenes

Aldiminium and 1,2,3-triazolium dithiocarboxylate zwitterions derived from cyclic (alkyl)(amino) and mesoionic carbenes

The synthesis of zwitterionic dithiocarboxylate adducts was achieved by deprotonating various aldiminium or 1,2,3-triazolium salts with a strong base, followed by the nucleophilic addition of the in situ-generated cyclic (alkyl)(amino) or mesoionic carbenes (CAACs or MICs) onto carbon disulfide. Nin...

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Bibliographic Details
Main Authors: Nedra Touj, François Mazars, Guillermo Zaragoza, Lionel Delaude
Format: Article
Language:English
Published: Beilstein-Institut 2023-12-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
betaines
carbenes
ligand effects
nitrogen heterocycles
zwitterions
Online Access:https://doi.org/10.3762/bjoc.19.145

Internet

https://doi.org/10.3762/bjoc.19.145

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