Thermal rearrangement of a 1,2-bis(silylene): Synthesis and crystal structure of a silyl-silylene
Thermal rearrangement of the 1,2-bis(silylene), [{(4-ButPh)C(NDip)2}Si−]2 (Dip = 2,6-diisopropylphenyl, leads to the silyl-silylene, {(4-ButPh)C(NDip)2}Si−Si(H) {N(Dip)C(=NDip)(4-ButPh-H)}, via an intramolecular C−H activation reaction. The X-ray crystal structure, and limited spectroscopic data, fo...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2019-07-01
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| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc-2019-0013 |