Study on the alcoholysis of dichloromethylvinylsilane(甲基乙烯基二氯硅烷乙醇解反应的研究)

对甲基乙烯基二氯硅烷的乙醇解反应进行了理论（采用B3LYP/6-31G(D)方法）和实验（溶剂法）研究，发现反应较容易进行.主产物为甲基乙烯基二乙氧基硅烷；反应宜按乙醇滴加入氯硅烷的方式进行.理论和实验结果比较吻合.计算溶剂效应，表明溶剂的存在有利于排除副产物HCI的干扰，阻碍副反应的进行....

Bibliographic Details
Main Authors:	XUWen-yuan(徐文媛), ZHONGYun(钟昀), LIUXian-liang(刘显亮), HEZhong-yi(何忠义), ZHENGLong-zhen(郑龙珍)
Format:	Article
Language:	zho
Published:	Zhejiang University Press 2007-07-01
Series:	Zhejiang Daxue xuebao. Lixue ban
Subjects:	甲基乙烯基二氯硅烷 b3lyp/6-31g（d）醇解溶剂效应
Online Access:	https://doi.org/zjup/1008-9497.2007.34.4.432-435

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