The Organic Ammonium Counterion Effect on Slow Magnetic Relaxation of the [Er(hfac)<sub>4</sub>]<sup>−</sup> Complexes

The Organic Ammonium Counterion Effect on Slow Magnetic Relaxation of the [Er(hfac)<sub>4</sub>]<sup>−</sup> Complexes

The first mononuclear anionic erbium complex [Er(hfac)<sub>4</sub>]<sup>−</sup> (hfac = hexafluoroacetylacetone) with an organic ammonium cation [(CH<sub>3</sub>)<sub>4</sub>N<sup>+</sup>] as the counterion was synthesized and structurally...

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Bibliographic Details
Main Authors: Tatiana G. Prokhorova, Denis V. Korchagin, Gennady V. Shilov, Alexei I. Dmitriev, Mikhail V. Zhidkov, Eduard B. Yagubskii
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Magnetochemistry
Subjects:
mononuclear complexes of rare earth elements with β-diketone ligands
ligand environment geometry
single-molecule magnets (SMMs)
slow magnetic relaxation
anisotropy barrier
Online Access:https://www.mdpi.com/2312-7481/9/6/159

Internet

https://www.mdpi.com/2312-7481/9/6/159

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