Inversion of Reactivity (umpolung) of Carbonyl Compounds Using Organosulfur Compounds Reagents
Organosulfur compounds have been exploited to reverse the reactivity of carbonyl compounds. The heteroatom produces a reactivity pattern in a carbon skeleton. Its electronegativity, being greater than that of carbon (-I effect) and its ability to stabilize an adjacent positive charge (+M effe...
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Format: | Article |
Language: | Arabic |
Published: |
Tishreen University
2018-11-01
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Series: | مجلة جامعة تشرين للبحوث والدراسات العلمية، سلسلة العلوم الأساسية |
Online Access: | http://journal.tishreen.edu.sy/index.php/bassnc/article/view/4632 |