Synthesis and crystal structure of poly[[bis(aqua-κO)tetrakis(μ-4,4′-bipyridine-κ2N:N′)hexakis(3-chlorobenzoato)-κ5O;κ2O:O′-tricobalt(II)] methanol disolvate]

Synthesis and crystal structure of poly[[bis(aqua-κO)tetrakis(μ-4,4′-bipyridine-κ2N:N′)hexakis(3-chlorobenzoato)-κ5O;κ2O:O′-tricobalt(II)] methanol disolvate]

A novel ladder-chain cobalt(II) coordination polymer, {[Co3(C7H4ClO2)6(C10H8N2)4(H2O)2]·2CH3OH}n, was synthesized and characterized. The structure contains two CoII centres with different octahedral environments, [Co(1)N3O3] and [Co(2)N2O4]. The O-donating 3-chlorobenzoate anions (3-Clbenz) act as t...

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Bibliographic Details
Main Authors: Phakamat Promwit, Kittipong Chainok, Nanthawat Wannarit
Format: Article
Language:English
Published: International Union of Crystallography 2022-03-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
cobalt(ii)
one-dimensional coordination polymer
ladder-chain structure
4,4′-bipyridine
3-clbenz
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989022000731

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989022000731

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