A new technique of arsenic determination based on electrolytic arsine generation and atomic absorption spectroscopy

Amethod for the determination of traces of arsenic in food has been developed based on electrolytic arsine generation and atomic absorption spectroscopy detection. The essence of the method is the addition of copper and tin salts to the electrolyte solution, enabling a fast and effective ar...

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Bibliographic Details
Main Authors: Ševaljević Mirjana M., Mentus Slavko V., Marjanović Nikola J.
Format: Article
Language:English
Published: Serbian Chemical Society 2001-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2001/0352-51390106419S.pdf
Description
Summary:Amethod for the determination of traces of arsenic in food has been developed based on electrolytic arsine generation and atomic absorption spectroscopy detection. The essence of the method is the addition of copper and tin salts to the electrolyte solution, enabling a fast and effective arsine evolution. The advantage of this method lies in the fact that it enables the simultaneous concentration of heavymetals, such as cadmium and lead, on cathode. The applicability of themethod was illustrated by determining the arsenic content in some food samples based on vegetable oils and by comparing the results with those obtained by the classical technique of chemical hydriding with sodium tetrahydroborate.
ISSN:0352-5139
1820-7421