Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions

A sequence of a Diels–Alder reaction and oxidation is a powerful route to valuable aromatic compounds. Here, the authors report a more atom-economical oxidant-free strategy involving a Diels–Alder with H2 evolution under noble-metal-free photoredox conditions.

Bibliographic Details
Main Authors: Guoting Zhang, Yulin Lin, Xu Luo, Xia Hu, Cong Chen, Aiwen Lei
Format: Article
Language:English
Published: Nature Portfolio 2018-03-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-018-03534-z