Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions
A sequence of a Diels–Alder reaction and oxidation is a powerful route to valuable aromatic compounds. Here, the authors report a more atom-economical oxidant-free strategy involving a Diels–Alder with H2 evolution under noble-metal-free photoredox conditions.
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2018-03-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-018-03534-z |
| _version_ | 1818990866070503424 |
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| author | Guoting Zhang Yulin Lin Xu Luo Xia Hu Cong Chen Aiwen Lei |
| author_facet | Guoting Zhang Yulin Lin Xu Luo Xia Hu Cong Chen Aiwen Lei |
| author_sort | Guoting Zhang |
| collection | DOAJ |
| description | A sequence of a Diels–Alder reaction and oxidation is a powerful route to valuable aromatic compounds. Here, the authors report a more atom-economical oxidant-free strategy involving a Diels–Alder with H2 evolution under noble-metal-free photoredox conditions. |
| first_indexed | 2024-12-20T20:01:10Z |
| format | Article |
| id | doaj.art-76c312ca639a4aee88981fedfed99abc |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-20T20:01:10Z |
| publishDate | 2018-03-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-76c312ca639a4aee88981fedfed99abc2022-12-21T19:28:03ZengNature PortfolioNature Communications2041-17232018-03-01911710.1038/s41467-018-03534-zOxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditionsGuoting Zhang0Yulin Lin1Xu Luo2Xia Hu3Cong Chen4Aiwen Lei5College of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan UniversityCollege of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan UniversityCollege of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan UniversityCollege of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan UniversityCollege of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan UniversityCollege of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan UniversityA sequence of a Diels–Alder reaction and oxidation is a powerful route to valuable aromatic compounds. Here, the authors report a more atom-economical oxidant-free strategy involving a Diels–Alder with H2 evolution under noble-metal-free photoredox conditions.https://doi.org/10.1038/s41467-018-03534-z |
| spellingShingle | Guoting Zhang Yulin Lin Xu Luo Xia Hu Cong Chen Aiwen Lei Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions Nature Communications |
| title | Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions |
| title_full | Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions |
| title_fullStr | Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions |
| title_full_unstemmed | Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions |
| title_short | Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions |
| title_sort | oxidative 4 2 annulation of styrenes with alkynes under external oxidant free conditions |
| url | https://doi.org/10.1038/s41467-018-03534-z |
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