Introducing Iodide Ligands on IrAu12 Cluster Enhances Phosphorescence Efficiency and Photoredox Activity

Introducing Iodide Ligands on IrAu12 Cluster Enhances Phosphorescence Efficiency and Photoredox Activity

Abstract The effects of halide ligands on the photoluminescence (PL) and photoredox properties were examined on [IrAu12(dppe)5X2]+ (1X; X=Cl, Br, I; dppe=1,2‐bis(diphenylphosphino)ethane). The PL quantum yield was enhanced in the order of 1Cl (67 %)<1Br (75 %)<1I (77 %). The lifetime of the ph...

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Bibliographic Details
Main Authors: Dr. Haru Hirai, Prof. Dr. Shinjiro Takano, Prof. Dr. Shinya Masuda, Prof. Dr. Tatsuya Tsukuda
Format: Article
Language:English
Published: Wiley-VCH 2024-03-01
Series:ChemElectroChem
Subjects:
Cluster compounds
Gold
Halides
Luminescence
Photoredox catalysis
Online Access:https://doi.org/10.1002/celc.202300669

Internet

https://doi.org/10.1002/celc.202300669

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