Chiral Discrimination Mechanisms by Silylated-Acetylated Cyclodextrins: Superficial Interactions vs. Inclusion

Chiral Discrimination Mechanisms by Silylated-Acetylated Cyclodextrins: Superficial Interactions vs. Inclusion

Cyclodextrin derivatives constitute a powerful class of auxiliary agents for the discrimination of apolar chiral substrates. Both host–guest inclusion phenomena and interactions with the derivatizing groups located on the surface of the macrocycle could drive the enantiodiscrimination; thus, it is i...

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Bibliographic Details
Main Authors: Federica Balzano, Gloria Uccello-Barretta, Giuseppe Sicoli, Letizia Vanni, Alessandra Recchimurzo, Federica Aiello
Format: Article
Language:English
Published: MDPI AG 2022-10-01
Series:International Journal of Molecular Sciences
Subjects:
NMR
diffusion coefficient
ROESY
association constant
chiral solvating agent
compound B
Online Access:https://www.mdpi.com/1422-0067/23/21/13169

Internet

https://www.mdpi.com/1422-0067/23/21/13169

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