A novel tetranucleate nickel (II)-based molecular catalytic system: Beneath visible light, highly effective and selective for CO2-to-CO transformation

Two kinds of easily synthesized, novel and excellent performance nickel(II)-based catalysts Ni4 [Ni4Cl8(tmphen)4(H2O)2] (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) and Ni-dmphen [NiCl2(4,7-dmphen)2] (dmphen = 4,7-dimethyl-1,10-phenanthroline) were obtained. Under visible light, a high turnove...

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Bibliographic Details
Main Authors: Xi-Bo Lu, Niang-Xiu Li, Yu-Mei Chen, Quan-Qing Xu, Zhi Yang
Format: Article
Language:English
Published: Elsevier 2022-10-01
Series:Catalysis Communications
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1566736722001091