Crystal structure of bis(μ-{2-[(5-bromo-2-oxidobenzylidene)amino]ethyl}sulfanido-κ3N,O,S){2,2′-[(3,4-dithiahexane-1,6-diyl)bis(nitrilomethanylylidene)]bis(4-bromophenolato)-κ4O,N,N′,O′}dicobalt(III) dimethylformamide monosolvate

Crystal structure of bis(μ-{2-[(5-bromo-2-oxidobenzylidene)amino]ethyl}sulfanido-κ3N,O,S){2,2′-[(3,4-dithiahexane-1,6-diyl)bis(nitrilomethanylylidene)]bis(4-bromophenolato)-κ4O,N,N′,O′}dicobalt(III) dimethylformamide monosolvate

The title binuclear CoIII complex, [Co2(C9H8BrNOS)2(C18H16Br2N2O2S2)]·C3H7NO, with a Schiff base ligand formed in situ from cysteamine (2-aminoethanethiol) and 5-bromosalicylaldehyde crystallizes in the space group P21. It was found that during the synthesis the ligand undergoes spontaneous oxidatio...

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Bibliographic Details
Main Authors: Julia A. Rusanova, Vladimir N. Kokozay, Olena Bondarenko
Format: Article
Language:English
Published: International Union of Crystallography 2019-06-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
binuclear CoIII complex
Schiff bases
5-bromosalicylaldehyde
cysteamine (2-aminoethanthiol)
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989019007217

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http://scripts.iucr.org/cgi-bin/paper?S2056989019007217

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