Azulene, Reactivity, and Scientific Interest Inversely Proportional to Ring Size; Part 1: The Five-Membered Ring

The lack of azulene symmetry with respect to the axis perpendicular to a molecule creates an asymmetry of the electronic system, increasing the charge density of the five-atom ring and favoring its electrophilic substitutions. The increased reactivity of this ring has contributed to ongoing interest...

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Bibliographic Details
Main Author: Alexandru C. Razus
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Symmetry
Subjects:
Online Access:https://www.mdpi.com/2073-8994/15/2/310